Emission Control and Air Pollution Module

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Partnership Illinois

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Day 2 Activities and Overview

Activities

Contact a local natural resource specialist from your local zoo or park and ask that person to tell you about the impact of vehicle emissions in the lakes, forests, or other natural resources in your area. (An alternative to this would be for the class to invite a specialist to come and speak on this topic.) Write down questions you want to ask this person and then write briefly what you have learned in a report to be given to the teacher or read to the class.

Contact a local architect or an architecture department in a local college or university and invite an architect to visit your classroom to describe how homes, schools, and office buildings are affected by the vehicle emissions. Write down his/her answers in a report to give to the teacher or read to the class.

Collect air pollution cartoons from newspapers and magazines. Display and discuss them.

Imagine that you are all scientists. Think about a research project to investigate some aspect of air pollution -- how it forms, the damage it does, etc.  Write your ideas on the board. Discuss the questions you would ask and the steps you would take to do the research. If possible, invite a local research scientist to the classroom to review your project and comment on it.


Automobile Emissions: An Overview

Emissions from an individual car are generally low, relative to the smokestack image many people associate with air pollution. But in numerous cities across the country, the personal automobile is the single greatest polluter, as emissions from millions of vehicles on the road add up. Driving a private car is probably a typical citizen's most "polluting" daily activity.

 

Sources of Auto Emissions

 

 

The power to move a car comes from burning fuel in an engine. Pollution from cars comes from by-products of this combustion process (exhaust) and from evaporation of the fuel itself.

 

The Combustion Process

Gasoline and diesel fuels are mixtures of hydrocarbons, compounds which contain hydrogen and carbon atoms. In a "perfect" engine, oxygen in the air would convert all the hydrogen in the fuel to water and all the carbon in the fuel to carbon dioxide. Nitrogen in the air would remain unaffected. In reality, the combustion process cannot be "perfect," and automotive engines emit several types of pollutants. Pollutants also escape into the air through fuel evaporation

"Perfect" Combustion:

FUEL (hydrocarbons) + AIR (oxygen and nitrogen) ==>> CARBON DIOXIDE + water + unaffected nitrogen

 

  Typical Engine Combustion:
FUEL + AIR ==>> UNBURNED HYDROCARBONS + NITROGEN OXIDES + CARBON MONOXIDE + CARBON DIOXIDE + water

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There are four major pollutants from vehicle emissions:

  HYDROCARBONS
Hydrocarbon emissions result when fuel molecules in the engine do not burn or burn only partially. Hydrocarbons react in the presence of nitrogen oxides and sunlight to form ground-level ozone, a major component of smog. Ozone irritates the eyes, damages the lungs, and aggravates respiratory problems. It is our most widespread and intractable urban air pollution problem. A number of exhaust hydrocarbons are also toxic, with the potential to cause cancer.

  NITROGEN OXIDES (NOx) 
Under the high pressure and temperature conditions in an engine, nitrogen and oxygen atoms in the air react to form various nitrogen oxides, collectively known as NOx. Nitrogen oxides, like hydrocarbons, are precursors to the formation of ozone. They also contribute to the formation of acid rain.

CARBON MONOXIDE
Carbon monoxide (CO) is a product of incomplete combustion and occurs when carbon in the fuel is partially oxidized rather than fully oxidized to carbon dioxide (CO ). Carbon monoxide reduces the flow of oxygen in the bloodstream and is particularly dangerous to persons with heart disease.
CARBON DIOXIDE
In recent years, the U.S. Environmental Protection Agency (EPA) has started to view carbon dioxide, a product of "perfect" combustion, as a pollution concern. Carbon dioxide does not directly impair human health, but it is a "greenhouse gas" that traps the earth's heat and contributes to the potential for global warming.

Fuel Evaporation

Hydrocarbon pollutants also escape into the air through fuel evaporation. With today's efficient exhaust emission controls and today's gasoline formulations, evaporative losses can account for a majority of the total hydrocarbon pollution from current model cars on hot days when ozone levels are highest. Evaporative emissions occur several ways:

DIURNAL: Gasoline evaporation increases as the temperature rises during the day, heating the fuel tank and venting gasoline vapors.
RUNNING LOSSES: The hot engine and exhaust system can vaporize gasoline when the car is running. 
HOT SOAK: The engine remains hot for a period of time after the car is turned off, and gasoline evaporation continues when the car is parked.  REFUELING: Gasoline vapors are always present in fuel tanks. These vapors are forced out when the tank is filled with liquid fuel.